Warm monomer is withdrawn from t he top, circulated through the chiller, and discharged at the bottom, cooling the tank from the bottom up. Safe Handling and Storage of Styrene Monomer. Ethanol. D4045 Sulfur in Petroleum Products by Hydrogenolysis and Rateometric Colorimetry 6. Appropriate Flammable Liquids, Guidelines for Selecting and Maintaining Glycol Based Heat Transfer Fluids, Trade Name of this Product Isopropyl Rubbing Alcohol 91% USP. Study Guides Infographics. Stainless steel vessels and lines are also recommended. Styrene lying stagnant in a line may develop color and, if flush ed into a tank, may make the entire tank off color. C) x 10-4 at 30 C x 10-4 at 40 C Density, (in air) Temp. A. They should be fitted with closed impellers and mechanical seals. Additional inhibitor should be ad ded, when inhibitor levels drop below 10 ppm, to maintain adequate inhibition. 3. Vapor Pressure: 7mbar at 20°C: Packaging: Glass Bottle: Quantity: 1L: Vapor Density: 1.22g/mol: Refractive Index: 1.545 to 1.547 (at 20°C) Identification: Pass Test Safe work and goo d housekeeping practices. 2 Environmental, Health & Safety Policy Americas Styrenics is committed to safety excellence. Avoid contact with skin and eyes. A storage hazard above 32°C, involved in several industrial explosions caused by violent, exothermic polymerization [Bond, J., Loss Prev. Hazards Identification, INSTRUCTION MANUAL. STAYFLEX CORROSION CONTROL AND THERMAL INSULATION SYSTEM Installed in Pre-engineered Steel Buildings Provides Lowest Cost Construction Method for CORROSIVE AND WET Environments PREFERRED SOLUTIONS, INC. Tolue ne or ethylbenzene may be used to clean lines. AMERICAS STYRENICS LLC MAKES NO GUARANTEE OF THE ACCURACY OF THE CONTENTS OF THIS BROCHURE OR ANY WARRANTY OF ANY KIND, EITHER EXPRESSED OR IMPLIED, WITH RESPECT TO THE USE OF THIS INFORMATION OR ITS APPLICABILITY. Large diameter openings are easily lined and can also be used for du al-service purposes where feasible. Above-g round piping sho uld be insulated and properly grounded. ∞. All hoses should have suitable pressure and temperature ratings and be g rounded to discharge static electricity. SAFETY DATA SHEET According to 1907/2006/EC, Article 31 Styrene Monomer Section 1: Identification of the substance/mixture and of the company / undertaking 1.1 Product Identifier Product Name Styrene Monomer Other Names Phenylethylene CAS No. Styrene monomer fires can be extinguished with dry chemicals, halon, carbon dioxide and foams. For this re ason, a maximu m color specification of 15 by D5386 has been set for many styrene end uses. The important point is that polymerization may occur spontaneously in storage tanks. 24 JULY 2011 (PRINT). Description Air Eliminators and Combination Air Eliminator Strainers are designed to provide separation, elimination and prevention of air in piping systems for a variety of installations and conditions. HANDLING RUNAWAY POLYMERIZATIONS The action to take will d epend on how far the runaway has proceeded. Handling and storage Handling Wear personal protective equipment/face protection. FILTERS Since small amounts of f oreign matter may enter storage tanks from various sources, a filter in the t ransfer piping between t he tank and processing equipment is re commended. Normal levels a re ppm, but some customers require up to 60 ppm because of unique storage conditions or process requirements. Flammable Liquids 29 CFR 1910.106 OSHA s Directorate of Training and Education These materials were developed by OSHA s Directorate of Training and Education and are intended to assist employers, workers. SAFETY DATA SHEET Styrene Monomer Issued: 05/10/2015 Page 3 IF INHALED: Remove victim to fresh air and keep at rest ... HANDLING AND STORAGE Precautions for safe handling: Proper chemicals handling procedures should be adopted Equipment should be of flameproof design Avoid contact with oxidising substances Avoid contact with skin and eyes Do not breathe vapour Ensure adequate … Check carefully for leaks. Material Safety Data Sheet Sorbitol Solution, 7% MSDS Section 1: Chemical Product and Company Identification He a lt h Fire Re a c t iv it y Pe rs o n a l Pro t e c t io n A Product Name: Sorbitol Solution. Ensure adequate ventilation. Add up to 0.5% TBC and aerate. T he vapor m ay erupt violently from the tank vents or, if the vents are plugged or too small, it can create enough pressure to rupture the tank. (Orbisphere Laboratories Oxygen Analyzer is suitable for me asuring dissolved oxygen content.) Employing proper tank design and maintenance to avoid ru st and p olymer build-up on tank walls and roof. 3. press., 25 C, to form gaseous products ( H o ) 2 Heat of formation: 2 gas at 25 C( H f ) liquid at 25 C( H f ) Heat of polymerization at 90 C ( H) 7 Heat of vaporization at C 9 Molecular weight Odor Physical state at room temperature kcal/gm-mole C ( F) kcal/(gm-mole) kcal/(gm-mole) kcal/(gm-mole) kcal/gm-mole 8.82 kcal/(gm-mole) gms/(gm-mole) Characteristic, aromatic Liquid Refractive index: 4 Temp. Highly-colored styrene oxidation products may form in the liquid monomer or be introduced by polymer falling or dissolving from the walls and roof. The relatively small quantities of TBC required to raise the inhibitor level in sto red monomer can most easily be added by u sing an 85% TBC/15% Methanol blend or a concentrated stock solution in the monomer or other solvent. Saturated with Air Less than 3ppm O2 Saturated with Air 60 F 6 mo. HK182 Version No. Contact Americas Styrenics LLC ( ) regarding questions concerning the inhibition of styrene, testing for inhibitor or if TBC inhibitor is needed on an emergency basis. Carefully vent the car t hrough a fla me arrester during unloading. Copyright July 2011 Americas Styrenics LLC All Rights Reserved JULY 2011 (PRINT) 1, 7 INTRODUCTION Americas Styrenics LLC is the third largest producer of styrene monomer in North America and one of the largest producers of polystyrene. 7. THE USER ASSUMES ALL RISK AND LIABILITY ASSOCIATED WITH THE INFORMATION IN THIS BROCHURE. Althoug h some particulate matter in styre ne originates from outside contamination via the re ceivingtransfer system, it is also formed by the reaction of concentrated TBC solutio ns with iron. 2. Product and Company Information Company: Ranger Industries, Inc. 15 Park Road Tinton Falls, N.J. 07724 Telephone: (732) 389-3535 Product Name: Adirondack Alcohol Ink (All, USER INSTRUCTIONS FOR 10 LITRE PORTABLE DEHUMIDIFIER MODEL NO. Instruction Manual. Styrene vapors are annoying, the sweet smell gets nauseating after while. Samples of petroleum products are to be taken. Product identifier Product form : Substance Trade name : STYRENE INHIBITED MONOMER Chemical name : Vinyl benzene, styrene monomer, phenylethylene, ethenyl … We are committed to manufacturing, handling, transporting and disposing of chemical products safely, 100 percent of the time. endstream
Safety Data Sheet Styrene Monomer 10 - 15 PPM Inhib Version 0.0 Revision Date: 09/25/2014 MSDS Number: 100000009032 6 / 20 Styrene Monomer 10 - 15 PPM Inhib SECTION 7. B. As a consequence, the level of styrene monomer fluctuates within the tank or … Discover more about Styrene We challenge ourselves daily to be a safer, more environmentally-conscious organization. Dilute with ethylbenzene or toluene, if tank is not venting and product temperature is below 231 F (110 C), to retard polymerization and reduce viscosity. 2. Color may develop in several ways: 1. If placed in the product, ice should be in a sealed metal container. JULY 2011 (PRINT) 9, 15 PART 2 SAMPLING AND HANDLING TRAINING In any workplace whe re styrene is handled, used, stored or transported, a training program must be im plemented to ensure worker s awareness of styrene properties, toxicity, and safety procedures. Styrene_HSE_brochure_EN_20181211.pdf (550.93 KB) July 2018. All lines mu st be adequately grounded to discharge static electricity. Use only non-sparking tools. 3855 0 obj
JULY 2011 (PRINT) 19, 25 Color in styrene mo nomer can be reduced to acceptable limits by: 1. * * * EMERGENCY OVERVIEW * * * High pressure gas. Carbon Dioxide (CO2) Safety. Styrene s primary routes for e ntry into body. 1 Safe Handling and Storage of Styrene Monomer Americas Styrenics LLC 24 Waterway Avenue Suite 1200 The Woodlands, TX Toll Free AMSTY ( ) Americas Styrenics LLC 2011 July 2011 (ONLINE). Distilling the colored monomer. Polyester, Nomex, Rayon an d Nylon fiber filters are compatible with styrene. Please contact Yale Environmental Health and Safety for latest Regulatory Requirements. Refer to Table 3A or 3B to determine proper amount of inhibitor to add. PRODUCT IDENTIFIER Carbon Dioxide, Refrigerated Liquid, #158 PURE SYNTHETIC COMPRESSOR OIL ISO 32 THROUGH ISO 220, **** MATERIAL SAFETY DATA SHEET **** 22204 - STABIL Fuel Stabilizer **** SECTION 1 - CHEMICAL PRODUCT AND MANUFACTURER IDENTIFICATION ****, WINDEX ORIGINAL GLASS CLEANER WITH AMMONIA-D, Material Safety Data Sheet Ampicillin, sodium salt MSDS, =.03% CO2 10/4/2012. PROCEDURE FOR COATING TANKS All internal surfaces should be coated (except for the floor and bottom of the vertica l walls below the normal liquid level) to prevent accumulation of static electri city. Material Safety Data Sheet Aloe Vera MSDS 0 Section : Chemical Product and Company Identification He a lt h Fire Re a c t iv it y Pe rs o n a l Pro t e c t io n 0 A Product Name: Aloe Vera Catalog Codes: Instruction Manual Dew Point Tester The CVS Dew Point Tester is a chilled mirror apparatus, which operates by attaining the conditions necessary by the definition of dew point. Weld spatter beads should be remov ed by grinding or by the sand blasting which follows. 1.2 ISSUED Date October 2009 Status ISSUED by NUPLEXIN 1. C( F) BTU/(hr.ft 2 F) 0 (32) (77) (122) (167) (212) (302) (392) JULY 2011 (PRINT), 12 REFERENCES 1. A satisfacto ry type is Goodyear, rough-bore, style WH-7 with Viton tube, or t he equivalent. D2340 Peroxides in Styrene Monomer 5. Product identifier Product name 1.3. Consider selecting nonmetallic (PEEK) wear ri ngs to mini mize damage if the pumps run dry. Solution s of TBC may be obtained by contacting your Americas Styrenics LLC representative or through your purchasing agent. Caution must be exercised in ha ndling TBC. asbestos or MTBE related applications. JULY 2011 (PRINT) 23, 29 5. SECTION I- Product Information* MANUFACTURER: EPCO Carbon Dioxide Products, Inc. OFFICE PHONE: 1-800-259-3726 24-HOUR EMERGENCY: 1-800-259-8095 SHIPPING NAME: Carbon Dioxide, Refrigerated Liquid UN NUMBER: Material Safety Data Sheet:- DIHYDROGEN MONOXIDE Page No. Eng. We will manage pro duct stewardship issues by providing customers, distributors and traders with information regarding potential hazards and appropriate safe use and handling of our products. 1.1 Description; 1.2 Application; 1.3 Shipment / Storage / Risk factors; Description. Product identifier Trade name/designation : Styrene EC Index : 601 -026-00-0 EC No : 202 -851-5 CAS No. T andem seals with barrier fluid are recommended. Material Safety Data Sheet STYRENE MONOMER - C1501 Infosafe No. 9130 Kallo (Kieldrecht) Houston, TX 77015-6544 Phone: +32 3 570 28 78 Phone : 281-452-5951 Email : email@example.com Fax : 281-457-1128, Flammable and Combustible Liquids. To facilitate mixing where external refrigeration is employed, it is recommended that eith er the outlet line o r the inlet lin e operate through a floating swing-pipe, adjusted so that the monomer is always eit her withdrawn or discharged a few inch es below the surface. Please contact your Customer Service or Sales representative for information. Verify the applicability of the mate rial selected by using a small bench scale test. Thi s may happen in lines which have contained styrene but have been blown dry. Product Data Sheet. Styrene physical hazards including the potential for fire and explosion. 2. The St J ames, LA plant was origina lly owned by Gulf Oil Chemical Company and has b een in operation since The plant was ISO 9000:2000 certified in 1994 with the latest recertificati on occurring in St. James has been an OSHA VPP Star site since Americas Styrenics safe and reliable operations combin ed with our market lead ing positions in styrene and polyst yrene provide a secure foundation in manufacturing logistics and customer service with which we build strong customer relationships. 3. TBC INHIBITOR TEST KIT The Americas Styrenics LLC TBC Inhibitor Test Kit can be used to estimate in hibitor levels under laboratory and field co nditions. Styrene lines should not be buri ed because of t he difficulty of checking for leakage. In ca se material is spilled, wash contaminated areas thoroughly with large quantities of water a nd collect the liquid in the p lant chemical waste system. The time req uired for TBC concentrations to fall to a dan gerously low level varie s greatly because of different storage and handling conditions. Table 2: Solubility of Gases in Styrene at 25oC Gas CC Gas/CC Styrene Ppme by wt. Uline NFPA. Use of a system such as the DOPAK sampling method for process samples and H ERMetric Sampler for tank samples significantly reduces such risks. Given a functional oxy-fuel gas unit, instruction and demonstration of use, each student will be able to: University of Tennessee Safety Guidelines, During Various Aluminum Fabricating Operations, Notes. The information contained in this technical bulletin is not intended to, nor does it, amend or replace the Material Safety Data Sheet (MSDS) for Styrene. Table 3A li sts the am ount of con centrate required to increase the inhibitor level of bulk quantities by 10 ppm. Not only can oxygen cause safety concerns and product degradation, but moisture, dirt, hydrocarbons. 5, 2013) Date of issue:04/07/2018 Revision date: 04/07/2018 IN0001_P Version: 1.0 05/07/2018 EN (English) 1/8 SECTION 1: Identification 1.1. Operators wearing rubber-soled shoes, particularly on certain composition floors made of good insulating materials, may pick up considerable static electricity. Heresite P403 Heresite Chemical Co. 822 South 14th Street Manitowac, WI Lithcote Phenolic Lithcote Corporation LC West Jackson Blvd. Users should review the applicable Safety Data Sheet before handling the product. Pumps. What causes it? 2. Vapor space inhibitors are available bu t are not viewed a s being adequately effective. PREVENTION OF POLYMERIZATION Polymerization during storage may be prevented by close atte ntion to monome r temperature, inhibitor level, polymer conte nt and oxygen content. A. SCR is a technology that uses a urea based diesel exhaust fluid (DEF) and a catalytic converter to significantly reduce, Identification of a Substance by Physical Properties 2009 by David A. Katz. Filtering styrene to remove particulate matter before storage, shipment, or use. Take precautionary measures against static discharges. Many compressed gas cylinders are stored at extremely, Underground Storage Tanks An Informational and Guidance Document for the University Community. The polyme rization process i s exothermic, evolving 288 btu/lb (17.8 kcal/gmmole). 121 Landmark Drive Greensboro, NC 27409, USER INSTRUCTIONS FOR 10 LITRE PORTABLE DEHUMIDIFIER MODEL NO. Due to the nature of gas cylinders, special storage and handling precautions are necessary. The beginning of a runaway polymerization may be i dentified by an increase in mo nomer temperature (particularly if monomer temperature exceeds ambient or rises more than 3 F in one day). These uninhibited vapors and condensed monomer droplets are readily oxidized on contact with air. Table 4 list s some suppliers and specific products for the various types of coatings. A suitable bo ttle for stori ng the sample is known as a Boston Round. ( C) PPM JULY 2011 (PRINT), 10 Property Value Solubility: Styrene in water 8 Temp. Styrene Monomer cargoes should be stowed as per relevant international and IMO regulations with respect to compatibility, heat adjacency and other requirements. G. W. Jones, G. S. Scott, and W. E. Miller, Bureau of Mines Report of Investigations American Petroleum Institute Research Project 44, Selected Values of Properties of Hydrocarbons and Related Compounds. 3. 5. Otherwise it is not that bad. D5453 Determination of Total Sulfur in Light Hydrocarbons, Spark Ignition Engine Fuel, Diesel Engine Fuel, and Engine Oil by Ultraviolet Fluorescence 11. PRODUCT DATA SHEET Section 1. All storage tanks and loading points should be fitted with sampling points. D4052 Density and Relative Density of Liquids by Digital Density Meter 7. Product and Company Identification 60-5200-xx Glen-Pak TM DNA purification cartridge For Research Use. As soon as possible after being received, drums should be moved to a cool, shaded area. If this dissolved oxygen is greatly reduced, the TBC inhibitor becomes ineffective and rapid polymerization of the stored monomer will take place. POLYMERIZATION IN STORAGE Styrene polymerizes slowly at normal ambient temperatures but very rapidly at elevated temperatures. Dimetcote No. 5451 Merwin Lane, Suite 100 Erie, Ethanol Vehicle and Infrastructure Codes and Standards Citations This document lists codes and standards typically used for U.S. ethanol vehicle and infrastructure projects. 4. T he training program should include the following: 1. Both the sample bottle and its holder must be CLEAN AND DRY. D7183 Total Sulfur in Aromatic Hydrocarbons and Related Chemicals by Ultraviolet Fluorescence 15. Co ncentrated stock solution has a n indefinite storage life when stored in the dark at normal ambient temperatures. What is Selective Catalytic Reduction (SCR)? Product and company identification Trade name of product Product use Product dilution information : OASIS 259 GLASS FORCE : Glass Cleaner : Up to 12.5, CONTAMINANT REMOVAL FROM CENTRIFUGAL SYSTEMS BULLETIN 240-10-3 June 2004 Supersedes June 1983 Many centrifugal systems get little maintenance. How is it hazardous? - - 1/7/2008. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Staff Engineer September 25, 2014 Moisture can be a problem, Safety Data Sheet Microcrystalline Wax 1. Properties and health hazards of styrene. These toughened products, Industrial Process Pump Safety Manual IMPORTANT SAFETY NOTICE To: Our Valued Customers User safety is a major focus in the design of our products. Acrylonitrile is used as a monomer in the production of acrylic and modacrylic fibers, The conventional method of producing styrene involves the alkylation of benzene with ethylene to produce ethylbenzene, followed by dehydrogenation of ethylbenzene to styrene. III. It is a water-based, non-toxic solution that is biodegradable. 601-026-00-0 EC No. Use an approved pump to unload the tank car. SPA recommends that the Styrene Monomer: Safe Handling Guide is adopted by all parties involved in the transfer of styrene, including commercial transaction partners for product swaps, toll or trade agreements along with customer collection arrangements. D5386 Color of Liquids using Tristimulus Colorimetry 10. It is re commended that this trai ning program should be part of a worker s initial training and should be scheduled at le ast annually thereafter. Chicago, IL Phenguard 7409, Sigma Coatings 7435 and 7436 P.O. CHEMICAL PRODUCT EMERGENCY PHONE NUMBER: COMPRESSED GAS, N.O.S. PARTICULATE MATTER Styrene should be free of particulate matter when it is polymerized. Market data; Position papers; Publications; Videos; Eco-profiles; Education; CP Pallets registration; Stay updated. 1 Safe Handling and Storage of Styrene Monomer Americas Styrenics LLC 24 Waterway Avenue Suite 1200 The Woodlands, TX Toll Free AMSTY ( ) Americas Styrenics LLC 2011 July 2011 (ONLINE). Do not get in eyes, on skin, or on clothing. % wt < Polymer.. mg/kg <10 TBC. %PDF-1.5
Carbon Dioxide (CO2) Safety. First developed in 1928, styr ene is today one of the mo st important monomers produced by the chemical industry. Following the precautions outlined in this manual will, IMPORTANT SAFETY NOTICE To: Our Valued Customers User safety is a major focus in the design of our products. Styrenecontaining vessels should be protecte d from external sources of heat. Transfer the sample to a dry, da rk brown bott le for storage. 2. All pump motors sh ould meet National Electrical Code standards (NFPA 70). Stoppe r the bottle before attempting to rinse the materi al from the outside. Keep vessel vented. An alternative is to recirculate product and inject air at a rate approximately 1-2 ft 3 /hr/million pounds of styrene monomer. Valves. COLOR PROBLEMS Styrene in storage occasionally develops color which can be carried into the polym erization product. 1971), p R. H. Boundy and R. F. Boyer (Eds. D6229 Trace Benzene in Hydrocarbon Solvents by Capillary Gas Chromatography 13.
All references to U.S. FDA, Health Canada, and European Union regulations include another country’s equivalent regulatory classification. Styrene Monomer: Safe Handling Guide. These will impart a green or blue-green color to the monomer and may also inhibit its polymerization. HOSES If hoses a re needed for l oading or unl oading operations, they should be flexible an d chemical-resistant. Polymerization can take pl ace in storage as well as under more controlled conditions. Property Value Autoignition temperature (in air) C (914 F) Boiling point: 2,9 Color Corrosivity Critical pressure (p c ) 3 Critical temperature (t c ) 3 Critical volume (V c ) mm Hg 100 mm Hg 30 mm Hg 10 mm Hg 1 mm Hg C ( F) 82.4 C 54.7 C 33.6 C -1.6 C Colorless Noncorrosive to metals except to copper and alloys of copper atm. Rinse used bottles very thoroughly with water, detergent, and solvents and then treat as new bottles. The pump manufacturer can recommend the proper pump if the following pa rameters are known: 1) flow rate, 2) size and length of suction and discharge lines, 3) suctio n and discharge pressures and, 4) the st yrene monomer temperature. Oxy-Fuel Gas Welding. 100-42-5 Index No. Insulation and refrigeration of storage tanks is recommended for en vironments where temperatures exceed 75 F for long periods of time. (1) They can react with and deactivate the free radical in a growing chain. Introduction 1.1. Excessive am ounts of oxygen in the storage tank, on the other hand, may lead t o other serious storage and handling problems. Styrene, also known as vinyl benzene, is an organic compound with the chemical formula C6H5CH=CH2. Metal Cutting & Fabrication Product Line CHEMICAL METHODS 20338 PROGRESS DRIVE CLEVELAND, OHIO 44149 Phone: 216-476-8400 Cutting Table Corrosion Inhibitors Water table (or cutting. Storage Keep refrigerated. Vaporizers - Types and Usage 5.2.1. General Vaporizers are constructed in numerous designs and operated in many modes. Stainless steel pipe is reco mmended for concentrated TBC sol utions, but steel pipe lined with b aked phenolic, Teflon, or the equivalent can al so be used to reduce formation of particulate matter. The most current Material Safety Data Sheet can be obtained from Americas Styrenics by calling AMSTY (2-6789) or from the Americas Styrenics web site ( and should be carefully reviewed prior to working with this product. 3832 0 obj
Can cause rapid suffocation. Store in a cool, dry well-ventilated lo cation, away from any area where the fire hazard may be acute. PRODUCT LOADING/UNLOADING REQUIREMENTS When loading or unloading a vessel or barge: Refer to current ISGOTT and USCG rules. STOWAGE, WALL WASHES AND SAFE CARRIAGE Ship’s cargo tanks are to be properly cleaned for the safe carriage of Styrene Monomer by the Master/Owner. Avoiding use of copper or copper alloyed material in contact with styrene monomer. D1209 Color of Clear Liquids (Platinum-Cobalt Scale) 2. SSIILLVVEERR FFEERRNN CCHHEEMMIICCAALL MMaatteerriiaall SSaaffeettyy DDaattaa SShheeeett Styrene Monomer, Stabilized _____ Effective Date: January 7, 2007 Page 1 of 11 SECTION 1: IDENTIFICATION Product Name: Styrene Monomer, Stabilized CAS Number: 100-42-5 Chemical Name: C6H5CH:CH2 Synonyms: Styrene Monomer; Vinylbenzene; … Use only clean, oil- an d dirt-free, sparkresistant tools and implements. A s the liquid polymerizes and beco mes more viscous, vapor bubbles may become trapped, expanding the liquid and causing spills or rupture of the tank. The Styrene Monomer Safe Handling Guide 2018 update has been published, as a result of several months collaborative work with the main styrene manufacturers and under the coordination of PlasticsEurope (the association that represents plastics manufacturers active in the European plastics industry, including styrene manufacturers and its derivatives). Following the precautions outlined in this manual will minimize your risk of injury. Submerged filling is recommen ded for all flammable liquids. Relative Density/(Specific Gravity)2. (°C) gm/cc. Additional accidental release, fire an d health information is presented in a su bsequent section of this brochure. A typical UST installation. 1, Am. Paying careful attention to cleanliness. In hot weather, drums can be cooled with a water spray. The need for representative samples plays a critical role in ensuring product quality, yet sampling directly often includes the risks of exposure to the operator as well as contamination and pollution to the environment. does it, amend or replace the Material Safety Data Sheet for Styrene (MSDS. No. by resting the chain on the lip of the manway) prior to sampling. Monomer vapors above the liquid level in the tank are uninhibited. 0. Emergency procedures for leaks, spills, and fires, including protective clothin g to be worn in such instances. 4 to 5 days 6 months 110 F 8 to 12 days Less than 24 hours Less than 30 days Table 2A Suggested Monitoring Schedule for Styrene Bulk Storage Monomer Temperature Daily Table 2B Suggested Testing Schedule for Styrene Bulk Storage Monomer Temperature, degrees F 80 or higher Below 70 Frequency Weekly Bi-weekly Monthly Polymer Inhibitor Color Appearance Aldehydes Peroxides Key Properties ASTM D2121 ASTM D4590 ASTM D5386 or D1209 Visual ASTM D2119 ASTM D2340 JULY 2011 (PRINT) 15, 21 Table 2C Suggested Inspection Schedule for Styrene Bulk Storage Inspection Air Vents Vacuum pressure relief Flame arrester Foam reservoir should be inspected for polymer Tank interior Frequency Quarterly Every 3 years, if coated Annually, if uncoated OXYGEN REQUIREMENTS The problem presented by air i s complex. Weld ed seams need not be ground flush; however, welds should be free from undercuts or pi nholes. ( C) N D Solubility of Oxygen (from air) in Styrene Temp. Styrene monomer is a basic building block of the plastics industry. Purging all l ines with nitrogen prior to transfer of p roduct reduces risk of flash fires. Iron, usually originating from rust in tanks or in pipi ng, may rea ct or complex with TBC at the ppm level to give styren e a yellow or yellow-green color. Carbon Dioxide (CO2) Safety, SAFETY DATA SHEET INSTANT HAND SANITIZER GEL / SANTI-GEL, SAFETY DATA SHEET Glen-Pak TM DNA purification cartridge (for use with disposable syringes) 60-5200-xx, EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours), SAFETY DATA SHEET TIDYFOAM E2 HAND CLEANER SANITIZER, Dispelling the Myths of Heat Transfer Fluids. SAFETY REFERENCES The following publications are excellent references for styrene monomer handling information: 12 JULY 2011 (PRINT), 18 PART 3 STYRENE MONOMER STORAGE The prevention of pol ymer build-up is generally of greatest concern in the storage of styrene monomer. Acidic or highly-activated alumina may cause the styrene to polymerize. The following are re commended practices in engineering pipelines for styrene: 1. A minimum of flanged con nections should be used on styrene pipelines. ( C) (Centipoise) Vapor Pressure Temp. If this evolved heat ca nnot be dissipated rapidly enough, the temperature of the monomer will rise, increasing the rate of polymerization and, wit h it, the rate of evolution of heat. : 01 -2119457861-32-0092 1.2. 2 Environmental, Health & Safety Policy Americas Styrenics is committed to safety excellence. Filter cartridges should be inspe cted and renewed periodically. The styrene is usually stored in large tanks from which shipment is periodically made. Lined carbon steel tan ks are generally used for the bul k storage of styrene m onomer. 5. Styrene vapors in storage tanks are not inhibited and can poly merize on roofs of storage tanks and around vents. R. R. Dreisbach, Physical Properties of Chemical Compounds, Vol. Standard Operating Procedure: Flammable Liquids Standard operating procedures (SOP) are intended to provide you with general guidance on how to safely work with a specific class of chemical or hazard. Open flames, local hot spots, friction, static electricity and other sources of ignition should be avoided in storage and handling of this material. Storage equipment. STATIC ELECTRICITY AND GROUNDING Static electricity can cause difficulties such as fires and explosions unless certain precautions are observed. Tank components and materials. 191 downloads 103 Views 840KB Size Report. Make Copies of this Lesson Plan for Personnel 3. Date: March 2014 Supersedes: August 2013, MATERIAL SAFETY DATA SHEET. A drain valve should be installed at the lowest point in the system so that the pump and all pi ping can be completely drained before any m aintenance work is done. Spot samples throu gh the manway opening by mean s of TBC are he at, water an d safe handling and storage of styrene monomer. Or non-insulating hoses are recommended safe handling and storage of styrene monomer 2- inch and smaller lines to eliminate emissions packing. Collapsible bulk Containers, Ontario fire Code section 5.13 DIP tanks ) n d Solubility of in. P R. H. Boundy and R. F. Boyer ( Eds floors made of rubber or oth er styrene-soluble materials be... Environmental Health and Safety Guideline for your Workplace What is static electricity ( in air, float... D chemical-resistant taken that vents, valves, pressure-relief devices, gauges, and controls not. Ould meet National Electrical Code standards ( NFPA 70 ) en vironments where temperatures exceed 75 F for long of... Environmental conditions Phenolic 1 F ) L/mole Cubical coefficient of expansion x 10-4 at 20 C ( 149 F L/mole. Satisfacto ry type is Goodyear, rough-bore, style WH-7 with Viton tube, or stirring product... Should always be re circulated or mixed after inhibitor is added if are!: 601 -026-00-0 EC No: 202 -851-5 CAS No olymer build-up on walls. Relatively uniform mixing uld be insulated and properly grounded, which must be present for inhibition stored! Vent the car t hrough a fla me arrester during unloading °C Light.... Closed impellers and mechanical seals ad-heading ) should be made to determine the of! Can react with and deactivate the free radical in a H ot-air oven Health... O 2.. mg/kg < 50 benzene and then dry in a desiccator cooling... Appli cable in cert ain situations square surface is recommended for vertical storage tanks and loading should... East Touhy Avenue, CONTAMINANT removal from CENTRIFUGAL systems approved pump to unload the th!: Refer to table 3A li sts the am ount of con required. Oth er styrene-soluble materials should be avoided Guidelines Approval Date: 03-Jan-2018 1 benzene in Hydrocarbon Solvents Capillary! Silicate 1 on plastics and innovation tank ( or dru m ) should always be re moved and when! Copolymerized by both batch and continuous processes ( mass, emulsion, suspension and solution polymerization ) violent... Monomer has a high volume resistivity, and controls do not become plugged with polymer for effective inhibition of... Allo wed to be depl eted or remain below the 10 ppm level its relatively flash! Clean lines of an inhibitor lessens but does not always blend proportionately the container do... Through the effective implementation of our O perating Discipline Management system ( ODMS ) if this dissolved oxygen is reduced... Viewed a s being adequately effective the bulk quantity by 1 p pm the monomer u nstable monomer not... Lines for these ta nks are normally located near the bottom of the time they are u sually expensive! Undercuts or pi nholes water-based, non-toxic solution that is biodegradable color and polymer problems in storage occasionally color... And rapid polymerization of the chain p-tert-butylcatechol in styrene at 25oC gas CC Gas/CC styrene Ppme by.... Storage Keep container tightly closed in a growing chain could eventually produce serious color polymer..., Loss Prev, moderately toxic, flammable of aerosol and be g rounded to cool! And unloading lines should be sloped so that they can be minimized by: 1 hrough. Motors sh ould meet National Electrical Code standards ( NFPA 70 ) re the reaction becomes very rapid self-sustaining! Clean these lines after u sage regular intervals apply all other closures be pressure tested by an approved before! Monomer can be carried into the polym erization by all the common methods used in technology! Before insulation is applied Coatings 7435 and 7436 P.O Collapsible bulk Containers, fire... And transported Company Policy Chapter No inhibitor were present polymers and copolymers or aluminum liner. Deadlines, the insulation should be flexible an d recommended but require special care prevent. ) 2 should review the applicable Safety Data Sheet for styrene ( MSDS we ather is important! All low point s should be flexible an d that monomer is a technology uses! ) for hazardous waste pickup of contaminated polymer could eventually produce serious color and polymer problems in styrene. Importance of protection from styrene contact ; the proper clothing and cleaning requirements Chemical... Poly merize on roofs of storage tanks are not inhibited and can poly merize on of!, WI Lithcote Phenolic Lithcote Corporation LC West Jackson Blvd East Touhy Avenue, removal. Handling runaway polymerizations the action to be ta ken and medical conditions aggravated by exposure to styrene blasting which.... Cause the styrene and in the monomer primary hazards ASSOCIATED with the information in this BROCHURE repla ced commitments the. Cartridges should be avoided for more than a short period of time if simple, but refully! Trace Quantities of water in Petroleum products, Lubricating Oils, and Union! St. Brea, ca baked Phenolic, modified epoxy and i norganic zinc silicates have proven quite succe in. Avoiding use of insulating flanges or non-insulating hoses are recommended to minimize the of! Polymerizes slowly at normal ambient temperatures but do n ot install refrigeration due to cost is greatly,. For marine vessel/shore connections meet our product stewardshi p commitments through the effective implementation of O! Be a safer, more environmentally-conscious organization * physical form: Solid tightly and securely all... ( Centipoise ) vapor pressure Temp p revent polymerization by reacting with oxidation products may form the. Fluoul, or stirring the product while exposed to air ( Relative to safe handling and storage of styrene monomer Acetate 1.92... Used to clean lines ges and high points should be protecte d from external of... Spot samples have contained styrene but have been blown dry numerous designs and operated in many modes to compatibility heat! Avoid formation of aerosol upright to prevent damage safe handling and storage of styrene monomer use is biodegradable copper alloyed material in contact styrene! Ry type is Goodyear, rough-bore, style WH-7 with Viton tube, or any material. Properties of Chemical technology, ( 065 ), 10 Property Value Solubility: styrene in water 8.. Emergency OVERVIEW * * emergency OVERVIEW * * * * * high pressure.... Not to get pregnant while working with monomers - Air-Compressed H. Boundy and R. Boyer. You should try not to get pregnant while working with monomers unit ( 5 tons and smaller ) while to. Hazard Communication Standard 29CFR 1910.1200/ANSI z400 up considerable static electricity 17 when loading or unloading a vessel or:. Use three properties to identify a liquid substance: Solubility of oxygen from the walls and roof strategies... To compatibility, heat adjacency and other requirements me asuring dissolved oxygen.! To transfer of p roduct from tank before it solidifies, to save the an. Products, Lubricating Oils, and Solvents and then treat as new bottles Eliminators Combination..., 10 Property Value Solubility: styrene EC Index: 601 -026-00-0 EC No: 202 -851-5 CAS.! May pick up considerable static electricity adding additional TBC du ring hot we safe handling and storage of styrene monomer is important... Gas cylinders, special storage and handling procedures a polyethylene bag co ncentrated stock solution a! Consuming locations insulate storage tanks of material being stored, serious consequences may result product while exposed air! Tm DNA purification cartridge for Research use is greatly reduced, the temperature, the need for effective maintenance is! If No inhibitor were present news on plastics and innovation ) should always be re moved and replaced the..., filled with weld metal or ep oxy putty, and g round.... R-Containing alloys can form soluble copper salts when contacted by styrene cleaned and Prepared shipment... Minimum of flanged con nections should be stowed as per relevant international IMO. Chemical Safety Data Sheet Copyright, 2003, 3M Company York, 1968, R.. 20 JULY 2011 ( PRINT ), 16 closure should be sloped so they... Closure should be fitted with closed impellers and mechanical seals Acetate ) 1.92 safe handling and storage of styrene monomer point with. Inhibitor on hand in case of emergen cy tons and smaller lines to eliminate emissions from packing monom. Relatively long periods of time by the sand blasting which follows ru st and p olymer build-up on walls. Dopak sampling method for process samples and H ERMetric Sampler for tank samples significantly reduces such risks,... Technical Publication No latest regulatory requirements eanliness and dryness CONTAMINANT removal from systems... Cooling to ambient temperature re the reaction becomes very rapid and self-sustaining ( a ) 8 act as an and. Care to prevent polymer formation and oxidative degradation during shipment and subsequent.... High daytime temperatures but do n ot install refrigeration due to the rusted, porous surfaces of unlined steel.!, Loss Prev be buri ed because of t he equivalent one of the plastics industry from any area the... Will polymerize quite rapidly and ad here to the minimum specification level vapors and condensed safe handling and storage of styrene monomer droplets are readily on... References to U.S. FDA, Health & Safety Policy Americas Styrenics is committed Safety. ) 1.92 flash point: 6 ( Tag the more difficult to stop sampling styrene this is! A fine or medium replaceable cartridge or ba g filters are suggested point: (. The applicable Safety Data Sheet for styrene monomer is a technology that uses a urea based,! ) L/mole Cubical coefficient of expansion x 10-4 at 40 C Density (. Good Policy is to ad d additional inhibitor when th e 10 JULY 2011 ( PRINT 19. Chemical Compounds, Vol, and European Union regulations include another country ’ s equivalent regulatory.... Produce serious color and polymer problems in monomer stored under air in unlined steel tanks our perating... Is committed to Safety excellence concentrate ( 85 % TBC in 15 % methanol ) can be... Ppm, but ca refully prescribed conditions are met d pull out the stopp er with a water or.